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Geoscientific Model Development An interactive open-access journal of the European Geosciences Union
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Discussion papers | Copyright
https://doi.org/10.5194/gmd-2018-8
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.

Model description paper 24 Jan 2018

Model description paper | 24 Jan 2018

Development of the city-scale chemistry transport model CityChem-EPISODE and its application to the city of Hamburg

Matthias Karl Matthias Karl
  • Chemistry Transport Modelling, Helmholtz-Zentrum Geesthacht, Geesthacht, Germany

Abstract. This paper describes the City-scale Chemistry (CityChem) extension of the urban dispersion model EPISODE with the aim to enable chemistry/transport simulations of multiple reactive pollutants on urban scales. The new model is called CityChem-EPISODE. The primary focus is on the simulation of urban ozone concentrations. Ozone is produced in photochemical reaction cycles involving nitrogen oxides (NOx) and volatile organic compounds (VOC) emitted by various anthropogenic activities in the urban area. The performance of the new model was evaluated with a series of synthetic tests and with a first application to the air quality situation in the city of Hamburg, Germany. The model performs fairly well for ozone in terms of temporal correlation and bias at the air quality monitoring stations in Hamburg. In summer afternoons, when photochemical activity is highest, modelled median ozone at an inner-city urban background station was about 30% lower than the observed median ozone. Inaccuracy of the computed photolysis frequency of nitrogen dioxide (NO2) is the most probable explanation for this. CityChem-EPISODE reproduces the spatial variation of annual mean NO2 concentrations between urban background, traffic and industrial stations. However, the temporal correlation between modelled and observed hourly NO2 concentrations is weak for some of the stations. For daily mean PM10, the performance of CityChem-EPISODE is moderate due to low temporal correlation. The low correlation is linked to uncertainties in the seasonal cycle of the anthropogenic particulate matter (PM) emissions within the urban area. Missing emissions from domestic heating might be an explanation for the too low modelled PM10 in winter months. Four areas of need for improvement have been identified: (1) dry and wet deposition fluxes; (2) treatment of photochemistry in the urban atmosphere; (3) formation of secondary inorganic aerosol (SIA); and (4) formation of biogenic and anthropogenic secondary organic aerosol (SOA). The inclusion of secondary aerosol formation will allow for a better sectorial attribution of observed PM levels. Envisaged applications of the CityChem-EPISODE model are urban air quality studies, environmental impact assessment, sensitivity analysis of sector-specific emission and the assessment of local and regional emission abatement policy options.

The discussion paper was formally withdrawn.
Matthias Karl
Interactive discussion
Status: closed
Status: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
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Interactive discussion
Status: closed
Status: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
Printer-friendly Version - Printer-friendly version Supplement - Supplement
Matthias Karl
Model code and software

City-scale Chemistry Transport Model CityChem-EPISODE (Release version 1.0) M. Karl https://doi.org/10.5281/zenodo.1116174

Matthias Karl
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The requested manuscript was not accepted for publication in Geoscientific Model Development and was retracted upon request of the authors.

Short summary
Urban air pollution issues in Europe are mainly related to the human health impacts of particulate matter and ozone. A large part of the population living in cities is exposed to ozone above the European Union air quality target. The new model CityChem-EPISODE has been developed to perform chemistry/transport simulations of multiple reactive pollutants in urban areas. The application of the model in Hamburg (Germany) in 2012 shows good performance for ozone at air quality monitoring stations.
Urban air pollution issues in Europe are mainly related to the human health impacts of...
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